Papers - DAIKO Yusuke

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  • Prevention of morphological change for (Ba,Sr)(Co,Fe)O3 cathodes by incorporating (Ce,Gd)O2 for intermediate-temperature solid oxide fuel cells Reviewed

    H. Sumi, K. Adachi, Y. Daiko

    Ceramics International   2024.07

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    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)  

    Other Link: https://doi.org/10.1016/j.ceramint.2024.07.317

  • Synthesis of highly dispersed metallic bismuth nanoparticles in CuO–Bi2O3–SiO2 glass-ceramics for sodium ion battery anode Reviewed

    M. Kuroiwa, F. Sato, T. Honma, Y. Daiko

    Journal of Solid State Chemistry   338   124838   2024.06

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    Authorship:Last author   Language:English   Publishing type:Research paper (scientific journal)  

    Other Link: https://doi.org/10.1016/j.jssc.2024.124838

  • Compositional design for SrTiO3 crystal precipitation from spinodal-type borosilicate glass containing large amounts of TiO2 Reviewed

    Kakeru Hattori, Masahiro Shimizu, Yusuke Daiko

    Journal of the Ceramic Society of Japan   131 ( 7 )   313 - 319   2023.07

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: https://doi.org/10.2109/jcersj2.23010

    DOI: https://doi.org/10.2109/jcersj2.23010

    Other Link: https://www.jstage.jst.go.jp/article/jcersj2/131/7/131_23010/_article

  • Proton implantation into living cells under nonvacuum atmosphere Reviewed

    R. Okawa, Y. Daiko, A. Obata, T. Kasuga

    AIP Advances   13   015111   2023.01

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    Authorship:Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    DOI: https://doi.org/10.1063/5.0131816

  • Ionic conduction of glasses and their potential applications Invited Reviewed International journal

    Yusuke Daiko, Atsushi Sakuda, Tsuyoshi Honma, Akitoshi Hayashi

    Journal of the Ceramic Society of Japan   130 ( 8 )   552   2022.08

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:https://www.jstage.jst.go.jp/article/jcersj2/130/8/130_22035/_article/-char/ja  

    Materials with high ionic conductivity are attracting a great deal of attention because they are indispensable for improving the performance of batteries, sensors, and capacitors. Solid electrolytes, in particular, have a potential to compensate for the shortcomings of liquid electrolytes, and are the subject of intense research and development worldwide. One of the big characteristics of glass is its high formability. Here we are focusing on glass-electrolytes. Differences between “superionic conductive glasses” and “ordinary glasses”, as well as the mixed alkali effect will be overviewed. In addition, glasses can retain large residual stress inside that can reach the order of several GPa depending on the cooling conditions. These residual stresses also affect ionic conductivity. Recent results on the application of glass formability and softening fluidity to the formation of interfaces in all-solid-state batteries, and to ion emission from sharpened glasses are reviewed.

    DOI: https://doi.org/10.2109/jcersj2.22035

    DOI: https://doi.org/10.2109/jcersj2.22035

    Other Link: https://www.jstage.jst.go.jp/article/jcersj2/130/8/130_22035/_pdf/-char/ja

  • Hydrogen adsorption and electronic structural calculation of a polymer-derived SiCH membrane with a unique affinity for molecular hydrogen International journal

    Yusuke Daiko, Yuji Iwamoto

    Journal of Sol-Gel Science and Technology   2022.07

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    Authorship:Lead author, Corresponding author  

    In order to understand the hydrogen affinity of polymer-derived SiCH membranes, the amount of adsorbed hydrogen molecules was measured near room temperature, and the stabilization energy for hydrogen adsorption was also calculated by first-principles calculations using the MP2 method. The energies of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO), the dipole moment of model molecules as well as the charge of the molecular hydrogen, and those relations to the hydrogen molecule affinity were investigated. A linear relationship was found between LUMO energy values and the minimum stabilization energy. It is suggested that a hydrocarbon ring (pore entrance) less than 1 nm on the surface of the SiCH membrane is important as an adsorption site of a hydrogen molecule.

    DOI: https://doi.org/10.1007/s10971-022-05876-z

    DOI: https://doi.org/10.1007/s10971-022-05876-z

    Other Link: https://link.springer.com/article/10.1007/s10971-022-05876-z

  • Determination of the activation volume for O2− ion conduction of YSZ via single-sweeping of load by utilizing an electrochemical indenter Reviewed International journal

    Yusuke Daiko, Junki Kato, Sawao Honda, Yuji Iwamoto

    Journal of the Ceramic Society of Japan   129 ( 10 )   616 - 618   2021.09

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    Authorship:Lead author, Corresponding author   Language:English   Publishing type:Research paper (scientific journal)  

    電導性を有する圧子を電極としても利用することで、圧子圧入と同時にインピーダンス測定を実施する電気化学圧子圧入法について研究しています。4GPaを超える局所高圧力場でのYSZの電気抵抗と応力・ひずみの関係を同時測定しました。有限要素法(COMSOL)による圧力場と電場のシミュレーションから、酸化物イオンが伝導する際の活性化体積を一回の圧入から決定することに成功しました。

    DOI: 10.2109/jcersj2.21128

    Other Link: https://www.jstage.jst.go.jp/article/jcersj2/129/10/129_21128/_article

  • Gas permeation and thermomechanical properties for macroporous alumina focused on necking size at grain boundaries Reviewed International coauthorship International journal

    S. Honda, P. Jia, Y. Daiko, S. Hashimoto, B. Nait-Ali, D. S. Smith, Y. Iwamoto

    International Journal of Applied Ceramic Technology   2021.08

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:WILEY  

    DOI: 10.1111/ijac.13860

  • Low temperature in situ formation of cobalt in silicon nitride toward functional nitride nanocomposites Reviewed International coauthorship

    S. Tada, M.D. Mallmann, H. Takagi, J. Iihama, N. Asakuma, T. Asaka, Y. Daiko, S. Honda, R.K. Nishihora, R.A.F. Machado, S. Bernard and Y. Iwamoto

    Chemical Communications   2021.01

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:Royal Society of Chemistry  

    DOI: 10.1039/d0cc07366k

    Other Link: https://pubs.rsc.org/en/content/articlelanding/2021/cc/d0cc07366k#!divAbstract

  • Hydrogen chemisorption properties of novel metal-free inorganic compound: exploring Lewis acid-base Al–N pair site formed in-situ within polymer-derived ceramics based on the silicon-aluminum-nitrogen-based system Reviewed International coauthorship

    S. Tada, N. Asakuma, S. Ando, T. Asaka, Y. Daiko, S. Honda, M. Haneda, S. Bernard, R. Riedel and Y. Iwamoto

    J. Mater. Chem. A   2020.12

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)  

  • Superhydrophobic polycarbosilane membranes for purification of solar hydrogen Reviewed International coauthorship International journal

    Miwako Kubo, Kohei Okibayash, Misako Kojima, Ryota Mano, Yusuke Daiko, Sawao Honda, Samuel Bernard and Yuji Iwamoto

    Sep. Purif. Technol   258 ( 1 )   117998 - 117998   2020.11

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: doi.org/10.1016/j.seppur.2020.117998

    Other Link: https://www.sciencedirect.com/science/article/pii/S1383586620324710?via%3Dihub

  • Kinetic Analysis of Crystallization of Zeolite Beta Synthesized by Direct Heating Reviewed International journal

    S. Honda, K. Nakashima, T. Yoshida, Y. Daiko, S. Hashimoto, Y. IwamotoO

    Journal of the American Ceramic Society   2020.10

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:WILEY  

    DOI: 10.1111/jace.17539

  • Hydrogen transport property of polymer-derived cobalt cation-doped amorphous silica Reviewed International coauthorship International journal

    Shotaro Tada, Shiori Ando, Toru Asaka, Yusuke Daiko, Sawao Honda, Samuel Bernard and Yuji Iwamoto

    Inorg. Chem. Front.   2020.10

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: doi. 10.1039/D0QI01035A

    Other Link: https://pubs.rsc.org/en/content/articlehtml/2020/qi/d0qi01035a

  • Fluoride ion field emission from a ZBLAC glass emitter Reviewed International journal

    Yusuke Daiko, Haruki Yanagida, Sawao Honda, Yuji Iwamoto

    Solid State Ionics   353   115400   2020.10

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:ELSEVIER  

    フッ化物イオン伝導性ガラスにIn2O3を添加したときのF-イオン伝導度向上について,残存酸素量やガラス転移温度,ラマンシフトなどから考察しています.また当該ガラスを先鋭化して高電圧を印加することで,F-イオン放出と思われる挙動を初めて確認しました.

    DOI: 10.1016/j.ssi.2020.115400

    Other Link: https://www.sciencedirect.com/science/article/pii/S0167273820304549?via%3Dihub

  • Hydrogen selective SiCH inorganic-organic hybrid/gamma-Al2O3 composite membranes Reviewed International coauthorship International journal

    Miwako Kubo, Ryota Mano, Misako Kojima, Kenichi Naniwa, Yusuke Daiko, Sawao Honda, Emanuel Ionescu, Samuel Bernard, Ralf Riedel and Yuji Iwamoto

    Membranes   10 ( 10 )   258 - 258   2020.09

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    Language:English   Publishing type:Research paper (scientific journal)  

    DOI: doi:10.3390/membranes10100258

    Other Link: https://www.mdpi.com/2077-0375/10/10/258

  • Dynamics of proton infiltration into binary MO・P2O5 (M=Ca, Sr) phosphate glasses Reviewed International journal

    Y. Daiko, S. Jeong, S.Honda, Y. Iwamoto

    Solid State Ionics   335   151 - 155   2019.03

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:ELSEVIER  

    溶融法で作製したガラスはプロトン(=OH基)濃度が低く、ガラスのプロトン伝導性は一般的に非常に低いです。以前に我々は燃料電池発電雰囲気に曝されることでガラスのプロトン伝導性が向上することを見出しています。燃料電池発電雰囲気を模擬した独自開発のin-situ赤外線分光装置を用いて、発電下でガラスのプロトン濃度が上昇するプロトン注入効果を初めて定量的に明らかにしました。論文では放射光X線による構造解析と合わせてプロトン注入を議論しています。

    DOI: 10.1016/j.ssi.2019.03.007

    Other Link: https://www.sciencedirect.com/science/article/pii/S0167273818307240

  • Palm-sized Ag+ ion emission gun operated at room temperature and non-vacuum atmosphere Reviewed International journal

    Y. Daiko, K. Segawa, K. Machida, H. Imataka, S. Honda, Y. Iwamoto

    Advanced Engineering Materials   20   1800198   2018.05

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:WILEY-V C H VERLAG GMBH  

    室温付近でも高いAg+イオン伝導性を示すAgI-Ag2O-B2O3ガラスを先鋭化して電界印加することで、室温かつ大気圧雰囲気においてもAg+イオン放出を確認しました。Ag+イオン放出寿命を電気化学水晶振動子微量天秤による電流値と振動数変化から議論しています。またAg+イオン照射後のガラス基板にはより多数のHeLa細胞が付着することを明らかにしました。兵庫県立大学との共同研究成果です。

    DOI: 10.1002/adem.201800198

    Other Link: https://onlinelibrary.wiley.com/doi/full/10.1002/adem.201800198

  • Void formation/elimination and viscoelastic response of polyphenylsilsesquioxane monolith Reviewed International journal

    Y. Daiko, Y. Oda, S. Honda, Y. Iwamoto

    materials   11 ( 5 )   846   2018.05

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:MDPI AG, Basel, Switzerland  

    SiO2(シリカ)はSiが4つの酸素で囲まれていますが、4つのうち一つをフェニル基に置き換えたものがフェニルシルセスキオキサン(PSQ)と呼ばれます。このPSQ粒子はゾル-ゲル法によって合成でき、粒子をガラス転移温度以上で加熱プレスすることで透明なバルク体に転移し、また絶縁性も比較的高いです。粒子→バルク転移時の変形挙動をin-situ解析したところ、粒子間にボイドが存在する場合は粘弾性挙動を示すのに対して、ボイドフリーのものは弾性変形すること、またボイドフリーの方がより高い絶縁耐圧を示すことを実験的に明らかにしました。

    DOI: 10.3390/ma11050846

    Other Link: http://www.mdpi.com/1996-1944/11/5/846?type=check_update&version=1

  • Ag+ ion emission from a sharp Ag2O-Al2O3-P2O5-SiO2 glass-fiber emitter Reviewed International journal

    Y. Daiko, K. Segawa, S. Honda, Y. Iwamoto

    Solid State Ionics   322   5 - 10   2018.04

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    Authorship:Lead author   Language:English   Publishing type:Research paper (scientific journal)   Publisher:ELSEVIER  

    成形性に優れるAg+イオン伝導性ガラスを溶融法で作製して、その先端を先鋭化して真空条件で高電圧を印加することで、ガラス先端からのAg+イオン放出を確認しました。イオン電流と電圧の関係はショットキープロットでよい直線性が見られ、Ag+イオン放出は熱電子放出と同じショットキーモデルで表されることが明らかとなりました。

    DOI: 10.1016/j.ssi.2018.04.018

    Other Link: https://www.sciencedirect.com/science/article/pii/S0167273818301784

  • Microporosity and CO2 Capture Properties of Amorphous Silicon Oxynitride Derived from Novel Polyalkoxysilsesquiazanes Reviewed

    Y. Iwase, Y. Horie, Y. Daiko, S, Honda, Y. Iwamoto

    materials   11   422 - 422   2018.03

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    Language:English   Publishing type:Research paper (scientific journal)  

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