Papers - DAIKO Yusuke
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Prevention of morphological change for (Ba,Sr)(Co,Fe)O3 cathodes by incorporating (Ce,Gd)O2 for intermediate-temperature solid oxide fuel cells Reviewed
H. Sumi, K. Adachi, Y. Daiko
Ceramics International 2024.07
Authorship:Last author Language:English Publishing type:Research paper (scientific journal)
Other Link: https://doi.org/10.1016/j.ceramint.2024.07.317
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Synthesis of highly dispersed metallic bismuth nanoparticles in CuO–Bi2O3–SiO2 glass-ceramics for sodium ion battery anode Reviewed
M. Kuroiwa, F. Sato, T. Honma, Y. Daiko
Journal of Solid State Chemistry 338 124838 2024.06
Authorship:Last author Language:English Publishing type:Research paper (scientific journal)
Other Link: https://doi.org/10.1016/j.jssc.2024.124838
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Compositional design for SrTiO3 crystal precipitation from spinodal-type borosilicate glass containing large amounts of TiO2 Reviewed
Kakeru Hattori, Masahiro Shimizu, Yusuke Daiko
Journal of the Ceramic Society of Japan 131 ( 7 ) 313 - 319 2023.07
Authorship:Corresponding author Language:English Publishing type:Research paper (scientific journal)
DOI: https://doi.org/10.2109/jcersj2.23010
DOI: https://doi.org/10.2109/jcersj2.23010
Other Link: https://www.jstage.jst.go.jp/article/jcersj2/131/7/131_23010/_article
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Proton implantation into living cells under nonvacuum atmosphere Reviewed
R. Okawa, Y. Daiko, A. Obata, T. Kasuga
AIP Advances 13 015111 2023.01
Authorship:Corresponding author Language:English Publishing type:Research paper (scientific journal)
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Ionic conduction of glasses and their potential applications Invited Reviewed International journal
Yusuke Daiko, Atsushi Sakuda, Tsuyoshi Honma, Akitoshi Hayashi
Journal of the Ceramic Society of Japan 130 ( 8 ) 552 2022.08
Authorship:Lead author, Corresponding author Language:English Publishing type:Research paper (scientific journal) Publisher:https://www.jstage.jst.go.jp/article/jcersj2/130/8/130_22035/_article/-char/ja
Materials with high ionic conductivity are attracting a great deal of attention because they are indispensable for improving the performance of batteries, sensors, and capacitors. Solid electrolytes, in particular, have a potential to compensate for the shortcomings of liquid electrolytes, and are the subject of intense research and development worldwide. One of the big characteristics of glass is its high formability. Here we are focusing on glass-electrolytes. Differences between “superionic conductive glasses” and “ordinary glasses”, as well as the mixed alkali effect will be overviewed. In addition, glasses can retain large residual stress inside that can reach the order of several GPa depending on the cooling conditions. These residual stresses also affect ionic conductivity. Recent results on the application of glass formability and softening fluidity to the formation of interfaces in all-solid-state batteries, and to ion emission from sharpened glasses are reviewed.
DOI: https://doi.org/10.2109/jcersj2.22035
DOI: https://doi.org/10.2109/jcersj2.22035
Other Link: https://www.jstage.jst.go.jp/article/jcersj2/130/8/130_22035/_pdf/-char/ja
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Hydrogen adsorption and electronic structural calculation of a polymer-derived SiCH membrane with a unique affinity for molecular hydrogen International journal
Yusuke Daiko, Yuji Iwamoto
Journal of Sol-Gel Science and Technology 2022.07
Authorship:Lead author, Corresponding author
In order to understand the hydrogen affinity of polymer-derived SiCH membranes, the amount of adsorbed hydrogen molecules was measured near room temperature, and the stabilization energy for hydrogen adsorption was also calculated by first-principles calculations using the MP2 method. The energies of the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO), the dipole moment of model molecules as well as the charge of the molecular hydrogen, and those relations to the hydrogen molecule affinity were investigated. A linear relationship was found between LUMO energy values and the minimum stabilization energy. It is suggested that a hydrocarbon ring (pore entrance) less than 1 nm on the surface of the SiCH membrane is important as an adsorption site of a hydrogen molecule.
DOI: https://doi.org/10.1007/s10971-022-05876-z
DOI: https://doi.org/10.1007/s10971-022-05876-z
Other Link: https://link.springer.com/article/10.1007/s10971-022-05876-z
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Determination of the activation volume for O2− ion conduction of YSZ via single-sweeping of load by utilizing an electrochemical indenter Reviewed International journal
Yusuke Daiko, Junki Kato, Sawao Honda, Yuji Iwamoto
Journal of the Ceramic Society of Japan 129 ( 10 ) 616 - 618 2021.09
Authorship:Lead author, Corresponding author Language:English Publishing type:Research paper (scientific journal)
電導性を有する圧子を電極としても利用することで、圧子圧入と同時にインピーダンス測定を実施する電気化学圧子圧入法について研究しています。4GPaを超える局所高圧力場でのYSZの電気抵抗と応力・ひずみの関係を同時測定しました。有限要素法(COMSOL)による圧力場と電場のシミュレーションから、酸化物イオンが伝導する際の活性化体積を一回の圧入から決定することに成功しました。
Other Link: https://www.jstage.jst.go.jp/article/jcersj2/129/10/129_21128/_article
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Gas permeation and thermomechanical properties for macroporous alumina focused on necking size at grain boundaries Reviewed International coauthorship International journal
S. Honda, P. Jia, Y. Daiko, S. Hashimoto, B. Nait-Ali, D. S. Smith, Y. Iwamoto
International Journal of Applied Ceramic Technology 2021.08
Authorship:Lead author Language:English Publishing type:Research paper (scientific journal) Publisher:WILEY
DOI: 10.1111/ijac.13860
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Low temperature in situ formation of cobalt in silicon nitride toward functional nitride nanocomposites Reviewed International coauthorship
S. Tada, M.D. Mallmann, H. Takagi, J. Iihama, N. Asakuma, T. Asaka, Y. Daiko, S. Honda, R.K. Nishihora, R.A.F. Machado, S. Bernard and Y. Iwamoto
Chemical Communications 2021.01
Authorship:Lead author Language:English Publishing type:Research paper (scientific journal) Publisher:Royal Society of Chemistry
DOI: 10.1039/d0cc07366k
Other Link: https://pubs.rsc.org/en/content/articlelanding/2021/cc/d0cc07366k#!divAbstract
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Hydrogen chemisorption properties of novel metal-free inorganic compound: exploring Lewis acid-base Al–N pair site formed in-situ within polymer-derived ceramics based on the silicon-aluminum-nitrogen-based system Reviewed International coauthorship
S. Tada, N. Asakuma, S. Ando, T. Asaka, Y. Daiko, S. Honda, M. Haneda, S. Bernard, R. Riedel and Y. Iwamoto
J. Mater. Chem. A 2020.12
Authorship:Lead author Language:English Publishing type:Research paper (scientific journal)
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Superhydrophobic polycarbosilane membranes for purification of solar hydrogen Reviewed International coauthorship International journal
Miwako Kubo, Kohei Okibayash, Misako Kojima, Ryota Mano, Yusuke Daiko, Sawao Honda, Samuel Bernard and Yuji Iwamoto
Sep. Purif. Technol 258 ( 1 ) 117998 - 117998 2020.11
Language:English Publishing type:Research paper (scientific journal)
DOI: doi.org/10.1016/j.seppur.2020.117998
Other Link: https://www.sciencedirect.com/science/article/pii/S1383586620324710?via%3Dihub
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Kinetic Analysis of Crystallization of Zeolite Beta Synthesized by Direct Heating Reviewed International journal
S. Honda, K. Nakashima, T. Yoshida, Y. Daiko, S. Hashimoto, Y. IwamotoO
Journal of the American Ceramic Society 2020.10
Authorship:Lead author Language:English Publishing type:Research paper (scientific journal) Publisher:WILEY
DOI: 10.1111/jace.17539
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Hydrogen transport property of polymer-derived cobalt cation-doped amorphous silica Reviewed International coauthorship International journal
Shotaro Tada, Shiori Ando, Toru Asaka, Yusuke Daiko, Sawao Honda, Samuel Bernard and Yuji Iwamoto
Inorg. Chem. Front. 2020.10
Language:English Publishing type:Research paper (scientific journal)
Other Link: https://pubs.rsc.org/en/content/articlehtml/2020/qi/d0qi01035a
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Fluoride ion field emission from a ZBLAC glass emitter Reviewed International journal
Yusuke Daiko, Haruki Yanagida, Sawao Honda, Yuji Iwamoto
Solid State Ionics 353 115400 2020.10
Authorship:Lead author Language:English Publishing type:Research paper (scientific journal) Publisher:ELSEVIER
フッ化物イオン伝導性ガラスにIn2O3を添加したときのF-イオン伝導度向上について,残存酸素量やガラス転移温度,ラマンシフトなどから考察しています.また当該ガラスを先鋭化して高電圧を印加することで,F-イオン放出と思われる挙動を初めて確認しました.
DOI: 10.1016/j.ssi.2020.115400
Other Link: https://www.sciencedirect.com/science/article/pii/S0167273820304549?via%3Dihub
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Hydrogen selective SiCH inorganic-organic hybrid/gamma-Al2O3 composite membranes Reviewed International coauthorship International journal
Miwako Kubo, Ryota Mano, Misako Kojima, Kenichi Naniwa, Yusuke Daiko, Sawao Honda, Emanuel Ionescu, Samuel Bernard, Ralf Riedel and Yuji Iwamoto
Membranes 10 ( 10 ) 258 - 258 2020.09
Language:English Publishing type:Research paper (scientific journal)
DOI: doi:10.3390/membranes10100258
Other Link: https://www.mdpi.com/2077-0375/10/10/258
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Dynamics of proton infiltration into binary MO・P2O5 (M=Ca, Sr) phosphate glasses Reviewed International journal
Y. Daiko, S. Jeong, S.Honda, Y. Iwamoto
Solid State Ionics 335 151 - 155 2019.03
Authorship:Lead author Language:English Publishing type:Research paper (scientific journal) Publisher:ELSEVIER
溶融法で作製したガラスはプロトン(=OH基)濃度が低く、ガラスのプロトン伝導性は一般的に非常に低いです。以前に我々は燃料電池発電雰囲気に曝されることでガラスのプロトン伝導性が向上することを見出しています。燃料電池発電雰囲気を模擬した独自開発のin-situ赤外線分光装置を用いて、発電下でガラスのプロトン濃度が上昇するプロトン注入効果を初めて定量的に明らかにしました。論文では放射光X線による構造解析と合わせてプロトン注入を議論しています。
DOI: 10.1016/j.ssi.2019.03.007
Other Link: https://www.sciencedirect.com/science/article/pii/S0167273818307240
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Palm-sized Ag+ ion emission gun operated at room temperature and non-vacuum atmosphere Reviewed International journal
Y. Daiko, K. Segawa, K. Machida, H. Imataka, S. Honda, Y. Iwamoto
Advanced Engineering Materials 20 1800198 2018.05
Authorship:Lead author Language:English Publishing type:Research paper (scientific journal) Publisher:WILEY-V C H VERLAG GMBH
室温付近でも高いAg+イオン伝導性を示すAgI-Ag2O-B2O3ガラスを先鋭化して電界印加することで、室温かつ大気圧雰囲気においてもAg+イオン放出を確認しました。Ag+イオン放出寿命を電気化学水晶振動子微量天秤による電流値と振動数変化から議論しています。またAg+イオン照射後のガラス基板にはより多数のHeLa細胞が付着することを明らかにしました。兵庫県立大学との共同研究成果です。
Other Link: https://onlinelibrary.wiley.com/doi/full/10.1002/adem.201800198
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Void formation/elimination and viscoelastic response of polyphenylsilsesquioxane monolith Reviewed International journal
Y. Daiko, Y. Oda, S. Honda, Y. Iwamoto
materials 11 ( 5 ) 846 2018.05
Authorship:Lead author Language:English Publishing type:Research paper (scientific journal) Publisher:MDPI AG, Basel, Switzerland
SiO2(シリカ)はSiが4つの酸素で囲まれていますが、4つのうち一つをフェニル基に置き換えたものがフェニルシルセスキオキサン(PSQ)と呼ばれます。このPSQ粒子はゾル-ゲル法によって合成でき、粒子をガラス転移温度以上で加熱プレスすることで透明なバルク体に転移し、また絶縁性も比較的高いです。粒子→バルク転移時の変形挙動をin-situ解析したところ、粒子間にボイドが存在する場合は粘弾性挙動を示すのに対して、ボイドフリーのものは弾性変形すること、またボイドフリーの方がより高い絶縁耐圧を示すことを実験的に明らかにしました。
DOI: 10.3390/ma11050846
Other Link: http://www.mdpi.com/1996-1944/11/5/846?type=check_update&version=1
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Ag+ ion emission from a sharp Ag2O-Al2O3-P2O5-SiO2 glass-fiber emitter Reviewed International journal
Y. Daiko, K. Segawa, S. Honda, Y. Iwamoto
Solid State Ionics 322 5 - 10 2018.04
Authorship:Lead author Language:English Publishing type:Research paper (scientific journal) Publisher:ELSEVIER
成形性に優れるAg+イオン伝導性ガラスを溶融法で作製して、その先端を先鋭化して真空条件で高電圧を印加することで、ガラス先端からのAg+イオン放出を確認しました。イオン電流と電圧の関係はショットキープロットでよい直線性が見られ、Ag+イオン放出は熱電子放出と同じショットキーモデルで表されることが明らかとなりました。
DOI: 10.1016/j.ssi.2018.04.018
Other Link: https://www.sciencedirect.com/science/article/pii/S0167273818301784
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Microporosity and CO2 Capture Properties of Amorphous Silicon Oxynitride Derived from Novel Polyalkoxysilsesquiazanes Reviewed
Y. Iwase, Y. Horie, Y. Daiko, S, Honda, Y. Iwamoto
materials 11 422 - 422 2018.03
Language:English Publishing type:Research paper (scientific journal)