Misc - YOSHIMIZU Hiroaki

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  • Gas Separation by Polymer Membranes Invited

    YOSHIMIZU Hiroaki

    Kobunshi (High Polymers, Japan)   67 ( 7 )   400 - 401   2018.07

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Publisher:The Society of Polymer Science, Japan  

    There is no strong interaction between polymers and
    gases. Therefore, it can be said that the general princple of gas-separation by polymer membranes is diffusion controlling not affinity tuning. Some unique polymer crystals were useful and had high-potential for gas-separation, because the interchain distances between polymer chains were well-adjusting to the size of gas molecules. In addition, these crystals showed diffusion anisotrpy. The enhancement of gas diffusion and permeation properties was confirmed by mono-axially orienting the crystal with a magnetic field. This method is one of the proposals to obtain a good gas-separation polymer membrane.

    Other Link: http://main.spsj.or.jp/c5/kobunshi/kobunshi.php

  • NMR Characterizations of Polymers Using Gases as Probes Invited Reviewed

    Hiroaki YOSHIMIZU

    J. Jpn. Soc. Colour Mater.   88 ( 8 )   265 - 270   2015.08

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Publisher:Japan Society of Colour Material (JSCM)  

    The gas transport properties (gas solubility, diffusivity and permeability) of polymer materials are directly influenced by their structural characteristics. In this article several studies wherein we obtained the NMR spectral data of polymer-gas systems are introduced. Namely, the gas sorption amount can be determined, detailed images of fine higher-ordered structures can be gained through the analysis of Xe-129 NMR chemical shifts, and clarification of the relationship between gas diffusion properties and the higher-ordered structures is possible.

    DOI: 10.4011/shikizai.88.265

  • Application of NMR Spectroscopy to the Characterization of Gas Separation Membranes

    Hiroaki Yoshimizu

    Sen'i Gakkaishi   68 ( 11 )   P_323 - P_328   2012.12

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (international conference proceedings)   Publisher:The Society of Fiber Science and Technology, Japan  

    DOI: 10.2115/fiber.68.P_323

  • Characterization of higher-odered structures of solid polymers by 129Xe NMR

    Hiroaki YOSHIMIZU

    Chemical Engineering   56 ( 8 )   636 - 643   2011.08

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Publisher:Kagaku Kogyosha, Inc.  

  • Function of Separation by Polymer Gas Separation by Using the Polymer Crystal

    H. Yoshimizu, Y. Tsujita

    Kobunshi (High Polymers, Japan)   54 ( 11 )   827 - 832   2005.11

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (international conference proceedings)   Publisher:The Society of Polymer Science, Japan  

  • Characterization of Polymers in the Solid State by 129Xe NMR Spectroscopy

    H. Yoshimizu, T. Suzuki, Y. Tsujita

    Sen'i Gakkaishi   60 ( 10 )   498 - 503   2004.10

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (international conference proceedings)   Publisher:The Society of Fiber Science and Technology, Japan  

  • Control of Gas Permeability for Cellulose Membrane by Microwavw Irradiation

    Y. Nakai, Y. Tsujita, H. Yoshimizu, S. Okamoto

    Cellulose Communications   11 ( 2 )   58 - 62   2004.02

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (international conference proceedings)   Publisher:The Cellulose Society of Japan  

  • Applications of NMR Spectroscopy to the Structure and Ionic Aggregates of Ionomers

    H.Yoshimizu, Y.Tsujita

    44   1 - 22   2001.07

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    Authorship:Lead author   Language:English   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Publisher:Academic Press  

    NMR法を用いたアイオノマーの研究例を最新の報告から紹介した.特にエチレンアイオノマーではイオン会合体の存在に加えてエチレンマトリックス相が結晶・非晶の両方を含み,複雑であるが,各種NMR法はこれの構造的知見を詳細に得る一つの有力な手段,との立場で解説した.

  • Gas sorption properties and fine structures of glassy polymers

    Hiroaki Yoshimizu, Yoshiharu Tsujita

    Polymer application   48 ( 12 )   541 - 547   1999.12

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Publisher:Kobunshi Knkoukai  

  • Gas permeation membranes of polyimides

    Yoshiharu Tsujita, Hiroaki Yoshimizu

    New Materials   7 ( 5 )   13 - 17   1996.05

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    Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Publisher:JAPAN INDUSTRIAL PUBLISHING CO., LTD.  

  • Gas permeation properties of the rigid polyimides

    Hiroaki Yoshimizu, Yoshiharu Tsujita

    Polymer Applications   45 ( 2 )   32 - 39   1996.02

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    Authorship:Lead author   Language:Japanese   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Publisher:Kobunshi Kankoukai  

  • NMR Studies of Higher-order Structures of Solid Polymers

    H. Kurosu, S. Ando, H. Yoshimizu, I. Ando

    28   189 - 275   1994.03

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    Language:English   Publishing type:Article, review, commentary, editorial, etc. (scientific journal)   Publisher:Academic Press Limited. Published by Elsevier Inc.  

    合成高分子から生体高分子まで様々な高分子を対象とした,各種固体NMR法を用いた研究例を242の文献とともに紹介した.

    DOI: 10.1016/S0066-4103(08)60093-9

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