SHIBATA Norio

写真a

Affiliation Department etc.

Department of Life Science and Applied Chemistry
Department of Life Science and Applied Chemistry

Title

Professor

 

Research Career

  • Design, Synthesis and Propaties of Phthalocyanines

    Individual   Grant-in-Aid for Scientific Research  

    Project Year:  2003.04  -  Now

  • Enantioselective Synthesis of Organofluorine Compounds

    Individual   Grant-in-Aid for Scientific Research  

    Project Year:  1988.04  -  Now

Papers

  • Direct nucleophilic trifluoromethylation of carbonyl compounds by potent greenhouse gas, fluoroform: Improving the reactivity of anionoid trifluoromethyl species in glymes

    Takuya Saito, Jiandong Wang, Etsuko Tokunaga, Seiji Tsuzuki, Norio Shibata

    Scientific Reports ( Springer Nature )  8   11501   2018.07  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • Highly C-selective difluoromethylation of β-ketoesters by using TMSCF2Br/lithium hydroxide/N,N,N-trimethylhexadecan-1-ammonium bromide

    Jiandong Wang, Etsuko Tokunaga, Norio Shibata

    Chemical Communications ( Royal Society of Chemistry )  54   8881 - 8884   2018.07  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • The CF3-DAST-induced deacylative trifluoromethylthiolation of cyclic 1,3-diketones/lactams/lactones and its extension to deacylative pentafluorophenylthiolation

    Ibrayim Saidalimu, Takuya Yoshioka, Yumeng Liang, Etsuko Tokunaga, Norio Shibata

    Chemical Communications ( Royal Society of Chemistry )  54   8761 - 8764   2018.07  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • A small-molecule inhibitor of SOD1-Derlin-1 interaction ameliorates pathology in an ALS mouse model

    Naomi Tsuburaya, Kengo Homma, Tsunehiko Higuchi, Andrii Balia, Hiroyuki Yamakoshi, Norio Shibata, Seiichi Nakamura, Hidehiko Nakagawa, Shin-ichi Ikeda他

    Nature Communications ( Nature )  9   2668   2018.07  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • Fluorobissulfonylmethyl Iodides: An Efficient Scaffold for Halogen Bonding Catalysts with an sp3-Hybridized Carbon-Iodine Moiety

    Kohei Matsuzaki, Hiroto Uno, Etsuko Tokunaga, Norio Shibata

    ACS Catalysis ( ACS Publications )  8 ( 7 ) 6601 - 6605   2018.06  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • Asymmetric synthesis of α-trifluoromethoxy ketones with a tetrasubstituted α-stereogenic centre via the palladium-catalyzed decarboxylative allylic alkylation of allyl enol carbonates

    Hiroya Kondo, Mayaka Maeno, Kazuki Hirano, Norio Shibata

    Chemical Communications ( Royal Society of Chemistry )  54 ( 44 ) 5522 - 5525   2018.06  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • Stille cross-coupling of secondary and tertiary α-(trifluoromethyl)-benzyl chlorides with allylstannanes

    Nagender Punna, Kyosuke Harada, Norio Shibata

    Chemical Communications ( Royal Society of Chemistry )  54 ( 52 ) 7171 - 7174   2018.06  [Refereed]

    Research paper (scientific journal)   Single Author

  • An eccentric rod-like linear connection of two heterocycles: Synthesis of pyridine trans-tetrafluoro-λ6-sulfanyl triazoles

    Prajwalita Das, Kiyoteru Niina, Tomoya Hiromura, Etsuko Tokunaga, Norimichi Saito, Norio Shibata

    Chemical Science ( Royal Society of Chemistry )  9 ( 22 ) 4931 - 4936   2018.05  [Refereed]

    Research paper (scientific journal)   Single Author

  • Modern Approaches for Asymmetric Construction of Carbon-Fluorine Quaternary Stereogenic Centers: Synthetic Challenges and Pharmaceutical Needs

    Yi Zhu, Jianlin Han, Jiandong Wang, Norio Shibata, Mikiko Sodeoka, Vadim A. Soloshonok, Jaime A. S. Coelho, F. Dean Toste

    Chemical Reviews ( ACS Publications )  118 ( 7 ) 3887 - 3964   2018.04

    Research paper (scientific journal)   Multiple Authorship

  • Stereodivergent trifluoromethylation of N-sulfinylimines by fluoroform with either organic-superbase or organometallic-base

    Nagender Punna, Takuya Saito, Mikhail Kosobokov, Etsuko Tokunaga, Yuji Sumiia, Norio Shibata

    Chemical Communications ( Royal Society of Chemistry )  54   4294 - 4297   2018.03  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

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Review Papers

  • Recent advancements in the synthesis of pentafluorosulfanyl (SF5)-containing heteroaromatic compounds

    Das, P.; Tokunaga, E.; Shibata, N

    Tetrahedron Lett. ( ELSEVIER )    2017.11  [Refereed]  [Invited]

    Introduction and explanation (scientific journal)   Multiple Authorship

  • Synthesis and application of trifluoroethoxy-substituted phthalocyanines and subphthalocyanines

    Satoru Mori, Norio Shibata

    Beilstein J. Org. Chem ( Beilstein )  13   2273 - 2296   2017.10  [Refereed]  [Invited]

    Introduction and explanation (scientific journal)   Multiple Authorship

  • Catalytic Asymmetric Synthesis of Enantioenriched Heterocycles Bearing a C CF3 Stereogenic Center

    Chemistry - A European Journal   21 ( 17 ) 8664 - 8684   2015.03

    Introduction and explanation (scientific journal)   Multiple Authorship

Presentations

  • Organocatalyzed trifluoromethylation of ketones and sulfonyl fluorides by fluoroform under superbase system

    Norio Shibata

    16th Tetrahedron Symposium Asia Edition  (Shanghai Institute of Organic Chemistry (Shanghai, China))  2015.11  -  2015.11 

  • Synthesis of Phthalocyanines having a Pentafluorosulfanyl Substitution at Peripheral Positions

    Norio Shibata

    KOST-2015 HETEROCYCLIC CONGRESS  (Lomonosov Moscow State University (Moscow, Russia))  2015.10  -  2015.10 

  • Synthesis of Diaryliodonium Salts for Trifluoromethanesulfonyl-Arylation

    Prajwalita Das,松崎浩平,徳永恵津子,柴田哲男

    第18回ヨウ素学会シンポジウム   (千葉大学(千葉))  2015.09  -  2015.09  ヨウ素学会

  • Synthesis and Property of Novel Phthalocyanine Having Pentafluorosulfanyl (SF5) Group on the Peripheral Positions

    Norio Shibata

    7th East Asia Symposium on Functional Dyes and Advanced Materials(EAS7)  (Osaka Prefecture University (Sakai, Japan))  2015.09  -  2015.09 

  • Synthesis of Phthalocyanines having a Pentafluorosulfanyl Substitution at Peripheral Positions

    Norio Shibata

    The Chemistry and Biological Activity of Synthetic and Natural Compounds(CBC2015)  (Beloselsky-Belozersky Palace (Saint-Petersburg, Russia))  2015.08  -  2015.09 

  • A Sterically Demanding Organo-superbase Avoids Decomposition of a Naked Trifluoromethyl Carbanion Directly Generated from Fluoroform

    Norio Shibata

    21stISFC&ISoFT'15  (Politecnico Di Milano (Como, Italy))  2015.08  -  2015.08 

  • Development of Novel Reagents for Electrophilic SF5-arylation

    Kohei Matsuzaki, Kenta Okuyama, Prajwalita Das, Etsuko Tokunaga, Norio Shibata

    The 3nd International Symposium on Process Chemistry (ISPC 2015)  (Kyoto International Conference Center (Kyoto, Japan))  2015.07  -  2015.07 

  • Trifluoromethylation using Fluoroform through Catalytic Amount of Phosphazene Base

    Satoshi Okusu, Kazuki Hirano, Etsuko Tokunaga, Norio Shibata

    The 3nd International Symposium on Process Chemistry (ISPC 2015)  (Kyoto International Conference Center (Kyoto, Japan))  2015.07  -  2015.07 

  • A Catalytic Synthetic Approach to HSD-016 Through Enantioselective Trifluoromethylation

    Yoshimasa Yasuda, Satoshi Okusu, Norio Shibata

    The 3nd International Symposium on Process Chemistry (ISPC 2015)  (Kyoto International Conference Center (Kyoto, Japan))  2015.07  -  2015.07 

  • Synthesis of phthalocyanines having a pentafluorosulfanyl substituion at peripheral positions

    Norio Shibata

    10th RUSSIAN CONFERENCE "FLUORINE CHEMISTRY"  (Tomsk Polytechnic University(Tomsk, Russia))  2015.06  -  2015.06 

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Work

  • Shibata reagent I, trifluoromethylation

    2012.01  -  Now

  • FBSM

    Artistic Activity  2008.01  -  Now

Academic Awards Received

  • CSJ Award for Creative Work in Chemical Society of Japan, 2015

    2015.03.28    

  • Prizes for Science and Technology, The Commendation for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology, 2014

    2014.04.15