SHIBATA Norio

写真a

Affiliation Department etc.

Department of Life Science and Applied Chemistry
Department of Life Science and Applied Chemistry

Title

Professor

 

Research Career

  • Design, Synthesis and Propaties of Phthalocyanines

    Individual   Grant-in-Aid for Scientific Research  

    Project Year:  2003.04  -  Now

  • Enantioselective Synthesis of Organofluorine Compounds

    Individual   Grant-in-Aid for Scientific Research  

    Project Year:  1988.04  -  Now

Papers

  • Synthesis of Chiral Nonracemic α-Difluoromethylthio Compounds with Tetrasubstituted Stereogenic Centers via a Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation

    Hiroya Kondo, Mayaka Maeno, Kenta Sasaki, Ming Guo, Masaru Hashimoto, Motoo Shiro, Norio Shibata

    Organic Letters ( ACS Publications )    2018.11  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • Defluorosilylation of Fluoroarenes and Fluoroalkanes

    Benqiang Cui, Shichong Jia, Etsuko Tokunaga, Norio Shibata

    Nature Communications ( Springer Nature )  9   4393   2018.10  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • Ortho-lithiation reaction of aryl-triflones

    Yuji Sumii, Misaki Taniguchi, Xiu-Hua Xu, Etsuko Tokunaga, Norio Shibata

    Tetrahedron ( Elsevier B.V )  74 ( 39 ) 5635 - 5641   2018.09  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • Super-Sensitive Protonation Behavior of Trifluoroethoxy-Substituted Phthalocyanines and Their Application to Solvent Discrimination

    Etsuko Tokunaga, Satoru Mori, Yuji Sumii, Norio Shibata

    ACS Omega ( ACS Publications )  3 ( 9 ) 10912 - 10917   2018.09  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • Design and synthesis of galactose-conjugated fluorinated and non-fluorinated proline oligomers: Towards antifreeze molecules

    Yuji Sumii, Hayata Hibino, Ibrayim Saidalimu, Hidehisa Kawahara, Norio Shibata

    Chemical Communications ( Royal Society of Chemistry )  54   9749 - 9752   2018.08  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • Direct nucleophilic trifluoromethylation of carbonyl compounds by potent greenhouse gas, fluoroform: Improving the reactivity of anionoid trifluoromethyl species in glymes

    Takuya Saito, Jiandong Wang, Etsuko Tokunaga, Seiji Tsuzuki, Norio Shibata

    Scientific Reports ( Springer Nature )  8   11501   2018.07  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • Highly C-selective difluoromethylation of β-ketoesters by using TMSCF2Br/lithium hydroxide/N,N,N-trimethylhexadecan-1-ammonium bromide

    Jiandong Wang, Etsuko Tokunaga, Norio Shibata

    Chemical Communications ( Royal Society of Chemistry )  54   8881 - 8884   2018.07  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • The CF3-DAST-induced deacylative trifluoromethylthiolation of cyclic 1,3-diketones/lactams/lactones and its extension to deacylative pentafluorophenylthiolation

    Ibrayim Saidalimu, Takuya Yoshioka, Yumeng Liang, Etsuko Tokunaga, Norio Shibata

    Chemical Communications ( Royal Society of Chemistry )  54   8761 - 8764   2018.07  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • A small-molecule inhibitor of SOD1-Derlin-1 interaction ameliorates pathology in an ALS mouse model

    Naomi Tsuburaya, Kengo Homma, Tsunehiko Higuchi, Andrii Balia, Hiroyuki Yamakoshi, Norio Shibata, Seiichi Nakamura, Hidehiko Nakagawa, Shin-ichi Ikeda他

    Nature Communications ( Springer Nature )  9   2668   2018.07  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

  • Fluorobissulfonylmethyl Iodides: An Efficient Scaffold for Halogen Bonding Catalysts with an sp3-Hybridized Carbon-Iodine Moiety

    Kohei Matsuzaki, Hiroto Uno, Etsuko Tokunaga, Norio Shibata

    ACS Catalysis ( ACS Publications )  8 ( 7 ) 6601 - 6605   2018.06  [Refereed]

    Research paper (scientific journal)   Multiple Authorship

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Review Papers

  • Inside front Cover: Asymmetric synthesis of α-trifluoromethoxy ketones with a tetrasubstituted α-stereogenic centre via the palladium-catalyzed decarboxylative allylic alkylation of allyl enol carbonates

    Hiroya Kondo, Mayaka Maeno, Kazuki Hirano, Norio Shibata

    Chemical Communications ( Royal Society of Chemistry )  54 ( 44 ) Inside front Cover - 5498   2018.06  [Refereed]

    Introduction and explanation (scientific journal)   Multiple Authorship

  • Front Cover: An eccentric rod-like linear connection of two heterocycles: Synthesis of pyridine trans-tetrafluoro-λ6-sulfanyl triazoles

    Prajwalita Das, Kiyoteru Niina, Tomoya Hiromura, Etsuko Tokunaga, Norimichi Saito, Norio Shibata

    Chemical Science ( Royal Society of Chemistry )  9 ( 22 ) Front Cover - 4921   2018.05  [Refereed]

    Introduction and explanation (scientific journal)   Multiple Authorship

  • Modern Approaches for Asymmetric Construction of Carbon-Fluorine Quaternary Stereogenic Centers: Synthetic Challenges and Pharmaceutical Needs

    Yi Zhu, Jianlin Han, Jiandong Wang, Norio Shibata, Mikiko Sodeoka, Vadim A. Soloshonok, Jaime A. S. Coelho, F. Dean Toste

    Chemical Reviews ( ACS Publications )  118 ( 7 ) 3887 - 3964   2018.04  [Refereed]

    Introduction and explanation (scientific journal)   Multiple Authorship

  • Front Cover: Access to benzo-fused nine-membered heterocyclic alkenes with a trifluoromethyl carbinol moiety via a double decarboxylative formal ring-expansion process under palladium catalysis

    Pulakesh Das, Satoshi Gondo, Punna Nagender, Hiroto Uno, Etsuko Tokunaga, Norio Shibata

    Chemical Science   9   Front Cover - 3257   2018.02  [Refereed]

    Introduction and explanation (scientific journal)   Multiple Authorship

  • Fluolead (Ar-SF3) Deoxofluorination

    Benqiang Cui, Norio Shibata

    Fluorination, Synthetic Organofluorine Chemistry ( Springer Singapore )    2018

    Introduction and explanation (scientific journal)   Multiple Authorship

  • Ar-SF4Cl Deoxofluorination

    Benqiang Cui, Norio Shibata

    Fluorination, Synthetic Organofluorine Chemistry ( Springer Singapore )    2018  [Refereed]

    Introduction and explanation (scientific journal)   Multiple Authorship

  • Front Cover Picture: Trifluoroethoxy-coated Subphthalocyanines Attract Small Arenes in their π-Concave Cavity

    Satoru Mori, Jiandong Wang, Etsuko Tokunaga, Motoo Shiro, Takashi Matsumoto, Seiji Tsuzuki, Norio Shibata

    ChemPlusChem   83 ( 3 ) Front Cover   2017.12  [Refereed]

    Introduction and explanation (scientific journal)   Multiple Authorship

  • Front Cover: Synthesis of pyridine trans-tetrafluoro-λ6-sulfane derivatives via radical additions

    Prajwalita Das, Masahiro Takada, Etsuko Tokunaga, Norimichi Saito, Norio Shibata

    Organic Chemistry Frontiers ( Royal Society of Chemistry )  5 ( 5 ) Front Cover   2017.11  [Refereed]

    Introduction and explanation (scientific journal)   Multiple Authorship

  • Recent advancements in the synthesis of pentafluorosulfanyl (SF5)-containing heteroaromatic compounds

    Das, P.; Tokunaga, E.; Shibata, N

    Tetrahedron Lett. ( ELSEVIER )    2017.11  [Refereed]  [Invited]

    Introduction and explanation (scientific journal)   Multiple Authorship

  • Synthesis and application of trifluoroethoxy-substituted phthalocyanines and subphthalocyanines

    Satoru Mori, Norio Shibata

    Beilstein J. Org. Chem ( Beilstein )  13   2273 - 2296   2017.10  [Refereed]  [Invited]

    Introduction and explanation (scientific journal)   Multiple Authorship

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Presentations

  • Story of SF5-substituted Pyridines

    Norio Shibata  [Invited]

    INTERNATIONAL CONGRESS ON PURE & APPLIED CHEMISTRY (ICPAC 2018)   (Sokhalay Angkor Resort & Spa( Siem Reap, Cambodia))  2018.03  -  2018.03 

  • Biological Evaluation of Both Enantiomers of Fluorothalidomide

    Norio Shibata  [Invited]

    Phar-East 2018  (Suntec Singapore (Singapore))  2018.03  -  2018.03 

  • Organocatalyzed trifluoromethylation of ketones and sulfonyl fluorides by fluoroform under superbase system

    Norio Shibata

    16th Tetrahedron Symposium Asia Edition  (Shanghai Institute of Organic Chemistry (Shanghai, China))  2015.11  -  2015.11 

  • Synthesis of Phthalocyanines having a Pentafluorosulfanyl Substitution at Peripheral Positions

    Norio Shibata

    KOST-2015 HETEROCYCLIC CONGRESS  (Lomonosov Moscow State University (Moscow, Russia))  2015.10  -  2015.10 

  • Synthesis of Diaryliodonium Salts for Trifluoromethanesulfonyl-Arylation

    Prajwalita Das,松崎浩平,徳永恵津子,柴田哲男

    第18回ヨウ素学会シンポジウム   (千葉大学(千葉))  2015.09  -  2015.09  ヨウ素学会

  • Synthesis and Property of Novel Phthalocyanine Having Pentafluorosulfanyl (SF5) Group on the Peripheral Positions

    Norio Shibata

    7th East Asia Symposium on Functional Dyes and Advanced Materials(EAS7)  (Osaka Prefecture University (Sakai, Japan))  2015.09  -  2015.09 

  • Synthesis of Phthalocyanines having a Pentafluorosulfanyl Substitution at Peripheral Positions

    Norio Shibata

    The Chemistry and Biological Activity of Synthetic and Natural Compounds(CBC2015)  (Beloselsky-Belozersky Palace (Saint-Petersburg, Russia))  2015.08  -  2015.09 

  • A Sterically Demanding Organo-superbase Avoids Decomposition of a Naked Trifluoromethyl Carbanion Directly Generated from Fluoroform

    Norio Shibata

    21stISFC&ISoFT'15  (Politecnico Di Milano (Como, Italy))  2015.08  -  2015.08 

  • Development of Novel Reagents for Electrophilic SF5-arylation

    Kohei Matsuzaki, Kenta Okuyama, Prajwalita Das, Etsuko Tokunaga, Norio Shibata

    The 3nd International Symposium on Process Chemistry (ISPC 2015)  (Kyoto International Conference Center (Kyoto, Japan))  2015.07  -  2015.07 

  • Trifluoromethylation using Fluoroform through Catalytic Amount of Phosphazene Base

    Satoshi Okusu, Kazuki Hirano, Etsuko Tokunaga, Norio Shibata

    The 3nd International Symposium on Process Chemistry (ISPC 2015)  (Kyoto International Conference Center (Kyoto, Japan))  2015.07  -  2015.07 

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Work

  • Shibata reagent I, trifluoromethylation

    2012.01  -  Now

  • FBSM

    Artistic Activity  2008.01  -  Now

Academic Awards Received

  • CSJ Award for Creative Work in Chemical Society of Japan, 2015

    2015.03.28    

  • Prizes for Science and Technology, The Commendation for Science and Technology by the Minister of Education, Culture, Sports, Science and Technology, 2014

    2014.04.15